The rate of the reaction 2NO + Cl₂ → 2NOCl is given by the rate equation rate = k[NO]²[Cl₂]. The…

The rate of the reaction $2NO + Cl_2 \rightarrow 2NOCl$ is given by the rate equation rate = $k[NO]^2[Cl_2]$. The value of the rate constant can be increased by
A Increasing the temperature
B Increasing the concentration of NO
C Increasing the concentration of the $Cl_2$
D Doing all of these

Detailed Solution

The rate constant k is characteristic of a reaction at a given temperature; it does not depend on the concentrations of the reactants.
Increasing [NO] or [$Cl_2$] increases the rate of the reaction, but the value of k stays the same.
The dependence of k on temperature is given by the Arrhenius equation: $k = Ae^{-E_a/RT}$
As T increases, $e^{-E_a/RT}$ increases, so k increases (roughly doubling for every 10 K rise).
Hence the rate constant can be increased by increasing the temperature.

Chemical Kinetics in past papers

54 questions from this chapter have appeared across 16 exam years.

Keep going

Practise Chemical Kinetics All 54 questions This chapter in 2010 AIPMT-MAINS