Given below are two statements: Statement I: [Co(NH₃)₆]³⁺ is a homoleptic complex whereas [Co(NH₃)₄Cl₂]⁺ is a heteroleptic complex. Statement II:…

Given below are two statements: Statement I: $[Co(NH_3)_6]^{3+}$ is a homoleptic complex whereas $[Co(NH_3)_4Cl_2]^{+}$ is a heteroleptic complex. Statement II: Complex $[Co(NH_3)_6]^{3+}$ has only one kind of ligands but $[Co(NH_3)_4Cl_2]^{+}$ has more than one kind of ligands. In the light of the above statements, choose the correct answer from the options given below:
A Statement I is true but Statement II is false.
B Statement I is false but Statement II is true.
C Both Statement I and Statement II are true.
D Both Statement I and Statement II are false.

Detailed Solution

$[Co(NH_3)_6]^{3+}$ has only one type of ligand ($NH_3$), so it is a homoleptic complex. $[Co(NH_3)_4Cl_2]^+$ has more than one type of ligand ($NH_3$ and $Cl^-$), so it is a heteroleptic complex. So both Statement I and Statement II are true.

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