2024 Re-NEET d and f Block ElementsAbsorption spectra of lanthanoids Medium Question 3 of 3 in d and f Block Elements

The UV-visible absorption bands in the spectra of lanthanoid ions are 'X', probably because of the excitation of electrons involving 'Y'. The 'X' and 'Y', respectively, are:

A Broad and $f$ orbitals
B Narrow and $f$ orbitals
C Broad and $d$ and $f$ orbitals
D Narrow and $d$ and $f$ orbitals

The answer is B.

Solution

In lanthanoids, the $4f$ orbitals are well shielded from the surroundings by the outer $5s$ and $5p$ electrons, so the $f$-$f$ transitions are only weakly perturbed by the ligand environment, producing narrow (sharp) absorption bands due to excitation of electrons within the $f$ orbitals.

Concept Absorption spectra of lanthanoids

d and f Block Elements in past papers

3 questions from this chapter have appeared across 1 exam years.