Limiting molar conductivity of NH₄OH (i.e. Λₘ°(NH₄OH)) is equal to:

3 2012 AIPMT-PRE ElectrochemistryKohlrausch's Law Easy
Limiting molar conductivity of $NH_4OH$ (i.e. $\Lambda_m^\circ(NH_4OH)$) is equal to:
A $\Lambda_m^\circ(NH_4Cl) + \Lambda_m^\circ(NaOH) - \Lambda_m^\circ(NaCl)$
B $\Lambda_m^\circ(NH_4Cl) + \Lambda_m^\circ(NaCl) - \Lambda_m^\circ(NaOH)$
C $\Lambda_m^\circ(NaOH) + \Lambda_m^\circ(NaCl) - \Lambda_m^\circ(NH_4Cl)$
D $\Lambda_m^\circ(NH_4OH) + \Lambda_m^\circ(NH_4Cl) - \Lambda_m^\circ(HCl)$

Detailed Solution

By Kohlrausch's law, $\Lambda_m^\circ(NH_4OH) = \lambda^\circ(NH_4^+) + \lambda^\circ(OH^-)$
$\Lambda_m^\circ(NH_4Cl) = \lambda^\circ(NH_4^+) + \lambda^\circ(Cl^-)$
$\Lambda_m^\circ(NaOH) = \lambda^\circ(Na^+) + \lambda^\circ(OH^-)$
$\Lambda_m^\circ(NaCl) = \lambda^\circ(Na^+) + \lambda^\circ(Cl^-)$
Adding the first two and subtracting the third cancels $Na^+$ and $Cl^-$:
$\Lambda_m^\circ(NH_4OH) = \Lambda_m^\circ(NH_4Cl) + \Lambda_m^\circ(NaOH) - \Lambda_m^\circ(NaCl)$

Kohlrausch's Law in past papers

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