The pK_b of dimethylamine and pKₐ of acetic acid are 3.27 and 4.77 respectively at T(K). The correct option for…

The $pK_b$ of dimethylamine and $pK_a$ of acetic acid are 3.27 and 4.77 respectively at $T$(K). The correct option for the pH of dimethylammonium acetate solution is:
A 5.50
B 7.75
C 6.25
D 8.50

Detailed Solution

Dimethylammonium acetate is a salt of a weak acid and a weak base: $pH = 7 + \frac{1}{2}pK_a - \frac{1}{2}pK_b$ $= 7 + \frac{1}{2}(4.77) - \frac{1}{2}(3.27) = 7 + 0.75 = 7.75$

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