Aluminium is extracted from alumina (Al₂O₃) by electrolysis of a molten mixture of:

Aluminium is extracted from alumina ($Al_2O_3$) by electrolysis of a molten mixture of:
A $Al_2O_3 + KF + Na_3AlF_6$
B $Al_2O_3 + HF + NaAlF_4$
C $Al_2O_3 + CaF_2 + NaAlF_4$
D $Al_2O_3 + Na_3AlF_6 + CaF_2$

Detailed Solution

In the Hall–Heroult process purified alumina is mixed with cryolite ($Na_3AlF_6$) and fluorspar ($CaF_2$).
These lower the melting point of the mixture and increase its conductivity.
So the molten mixture is $Al_2O_3 + Na_3AlF_6 + CaF_2$.

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