In Lassaigne's extract of an organic compound, both nitrogen and sulphur are present, which gives blood red colour with Fe³⁺…

In Lassaigne's extract of an organic compound, both nitrogen and sulphur are present, which gives blood red colour with $Fe^{3+}$ due to the formation of
A $[Fe(SCN)]^{2+}$
B $Fe_4[Fe(CN)_6]_3\cdot xH_2O$
C $NaSCN$
D $[Fe(CN)_5NOS]^{4-}$

Explanation

When N and S are both present, $NaSCN$ forms and gives $[Fe(SCN)]^{2+}$ (blood red) with $Fe^{3+}$.

Detailed Solution

In case nitrogen and sulphur both are present in an organic compound, sodium thiocyanate is formed. $Na+C+N+S\rightarrow NaSCN$ Which further reacts as: $Fe^{3+}+SCN^-\rightarrow[Fe(SCN)]^{2+}$ (blood red colour)

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