Which ion is colourless :

Which ion is colourless :
A $Cr^{4+}$
B $Sc^{3+}$
C $Ti^{3+}$
D $V^{3+}$

Detailed Solution

The colour of transition metal ions arises from d–d transitions, which need partly filled d orbitals.
$Sc^{3+}$: $3d^0$ (no d electrons), so no d–d transition is possible, and it is colourless.
$Ti^{3+}$ ($3d^1$, purple), $V^{3+}$ ($3d^2$, green) and $Cr^{4+}$ ($3d^2$) have unpaired d electrons and are coloured.
So $Sc^{3+}$ is colourless.

Colour of transition metal ions in past papers

4 questions from this chapter have appeared across 4 exam years.

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Practise Colour of transition metal ions All 4 questions This chapter in 2000 AIPMT