Sulphur trioxide can be obtained by which of the following reaction:

42 2012 AIPMT-PRE The p-Block ElementsOxides of sulphur Medium
Sulphur trioxide can be obtained by which of the following reaction:
A $H_2SO_4 + PCl_5 \xrightarrow{\Delta}$
B $CaSO_4 + C \xrightarrow{\Delta}$
C $Fe_2(SO_4)_3 \xrightarrow{\Delta}$
D $S + H_2SO_4 \xrightarrow{\Delta}$

Detailed Solution

$Fe_2(SO_4)_3 \xrightarrow{\Delta} Fe_2O_3 + 3SO_3$
$H_2SO_4 + PCl_5$ gives sulphuryl chloride/chlorosulphonic acid, $CaSO_4 + C$ gives $SO_2$ (or CaS), and $S + 2H_2SO_4 \rightarrow 3SO_2 + 2H_2O$.
So $SO_3$ is obtained by heating ferric sulphate.

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