2004 AIPMT ThermodynamicsEntropy and Spontaneity Easy Question 2 of 2 in Entropy and Spontaneity

Considering entropy (S) as a thermodynamic parameter, the criterion for the spontaneity of any process is :-

A $\Delta S_{system} - \Delta S_{surroundings} \gt 0$
B $\Delta S_{system} \gt 0$ only
C $\Delta S_{surroundings} \gt 0$ only
D $\Delta S_{system} + \Delta S_{surroundings} \gt 0$

The answer is D.

Solution

According to the second law of thermodynamics, a process is spontaneous if the total entropy of the universe increases.
$\Delta S_{total} = \Delta S_{universe} = \Delta S_{system} + \Delta S_{surroundings}$
For a spontaneous process: $\Delta S_{system} + \Delta S_{surroundings} \gt 0$. At equilibrium $\Delta S_{total} = 0$.
Entropy of the system alone or of the surroundings alone is not enough; for example, freezing of water below $0^\circ C$ is spontaneous although $\Delta S_{system}$ is negative, because $\Delta S_{surroundings}$ is larger and positive.
So the criterion is $\Delta S_{system} + \Delta S_{surroundings} \gt 0$.

Concept Second law criterion of spontaneity

Entropy and Spontaneity in past papers

2 questions from this chapter have appeared across 2 exam years.