In X–H ----- Y, X and Y both are electronegative elements : -

In X–H ----- Y, X and Y both are electronegative elements : -
A Electron density on X will increase and on H will decrease
B In both electron density will increase
C In both electron density will decrease
D On X electron density will decrease and on H increases

Detailed Solution

In a hydrogen bond X–H$\cdots$Y, the hydrogen atom is covalently bonded to the strongly electronegative atom X.
X pulls the shared electron pair towards itself, so X gets a partial negative charge (electron density increases on X) and H gets a partial positive charge (electron density on H decreases): $X^{\delta-}-H^{\delta+}$.
This partially positive H is then attracted by the lone pair of the electronegative atom Y of another molecule, forming the hydrogen bond.
So electron density on X will increase and on H will decrease.

Hydrogen Bonding in past papers

2 questions from this chapter have appeared across 2 exam years.

Keep going

Practise Hydrogen Bonding All 2 questions This chapter in 2001 AIPMT