The order of energy absorbed which is responsible for the color of complexes A. [Ni(H₂O)₂(en)₂]²⁺ B. [Ni(H₂O)₄(en)]²⁺ and C. [Ni(en)₃]²⁺…

The order of energy absorbed which is responsible for the color of complexes A. $[Ni(H_2O)_2(en)_2]^{2+}$ B. $[Ni(H_2O)_4(en)]^{2+}$ and C. $[Ni(en)_3]^{2+}$ is
A B > A > C
B A > B > C
C C > B > A
D C > A > B

Detailed Solution

en (ethylenediamine) is a stronger field ligand than $H_2O$. As the number of en ligands increases, the crystal field splitting $\Delta_o$ increases, so the energy absorbed increases. $[Ni(en)_3]^{2+}$ (3 en) > $[Ni(H_2O)_2(en)_2]^{2+}$ (2 en) > $[Ni(H_2O)_4(en)]^{2+}$ (1 en) So the order is C > A > B.

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