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Coordination Compounds
Crystal Field Theory – Colour of Complexes
1 question from 1 paper, each with its answer.
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- years asked, 2017–2026
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- of Coordination Compounds
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Concepts tested
- spectrochemical series and energy absorbed
All Questions
2022 1 question
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The order of energy absorbed which is responsible for the color of complexes A. $[Ni(H_2O)_2(en)_2]^{2+}$ B. $[Ni(H_2O)_4(en)]^{2+}$ and C. $[Ni(en)_3]^{2+}$ isen (ethylenediamine) is a stronger field ligand than $H_2O$. As the number of en ligands increases, the crystal field splitting $\Delta_o$ increases, so the energy absorbed increases. $[Ni(en)_3]^{2+}$ (3 en) > $[Ni(H_2O)_2(en)_2]^{2+}$ (2 en) > $[Ni(H_2O)_4(en)]^{2+}$ (1 en) So the order is C > A > B.
