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The most suitable method of separation of 1 : 1 mixture of ortho and para-nitrophenols is
Explanation
o-Nitrophenol is steam volatile due to intramolecular H-bonding.
Detailed Solution
Steam distillation is the most suitable method of separation of a 1 : 1 mixture of ortho and para nitrophenols, as there is intramolecular H-bonding in ortho-nitrophenol, making it steam volatile.