KMnO₄ can be prepared from K₂MnO₄ as per the reaction: 3MnO₄²⁻ + 2H₂O ⇌ 2MnO₄⁻ + MnO₂ + 4OH⁻. The…

$KMnO_4$ can be prepared from $K_2MnO_4$ as per the reaction: $3MnO_4^{2-} + 2H_2O \rightleftharpoons 2MnO_4^- + MnO_2 + 4OH^-$. The reaction can go to completion by removing $OH^-$ ions by adding:
A $SO_2$
B HCl
C KOH
D $CO_2$

Detailed Solution

$CO_2$ is acidic and removes $OH^-$ ions: $2OH^- + CO_2 \rightarrow CO_3^{2-} + H_2O$, which drives the reaction to completion.
HCl cannot be used because it is oxidised by $KMnO_4$, and $SO_2$ is a reducing agent.

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Practise Potassium permanganate All 2 questions This chapter in 2013 NEET