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The p-Block Elements (Group 13 and 14)
Carbon Family – Anomalous Behaviour and Covalence of Silicon
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Concepts tested
- stability of hexa-coordinated species
All Questions
2019 1 question
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Which of the following species is not stable?Due to the presence of d-orbitals in Si, Ge and Sn, they form species like $[SiF_6]^{2-}$, $[GeCl_6]^{2-}$ and $[Sn(OH)_6]^{2-}$. $[SiCl_6]^{2-}$ does not exist because six large chloride ions cannot be accommodated around $Si^{4+}$ due to its small size.
