The variation of the boiling points of the hydrogen halides is in the order HF > HI > HBr >…

32 2015 AIPMT-II The p-Block ElementsHydrogen halides Easy
The variation of the boiling points of the hydrogen halides is in the order HF > HI > HBr > HCl. What explains the higher boiling point of hydrogen fluoride?
A The bond energy of HF molecules is greater than in other hydrogen halides
B The effect of nuclear shielding is much reduced in fluorine which polarises the HF molecule
C The electronegativity of fluorine is much higher than for other elements in the group
D There is strong hydrogen bonding between HF molecules

Detailed Solution

HF molecules are associated through strong hydrogen bonding, so HF has the highest boiling point: HF > HI > HBr > HCl.

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