Preparation of haloalkanes

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Concepts tested here

  • Lucas reagent and alcohol reactivity

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2015 AIPMT-II 1 question

  1. Which of the following reaction(s) can be used for the preparation of alkyl halides?
    (I) $CH_3CH_2OH + HCl \xrightarrow{anh.\ ZnCl_2}$
    (II) $CH_3CH_2OH + HCl \rightarrow$
    (III) $(CH_3)_3COH + HCl \rightarrow$
    (IV) $(CH_3)_2CHOH + HCl \xrightarrow{anh.\ ZnCl_2}$