Solution

Interference, diffraction and polarisation can be explained only by the wave nature of light. Refraction can be explained by the wave theory too.
The photoelectric effect (instant emission, threshold frequency, and kinetic energy depending on frequency but not intensity) cannot be explained by waves.
Einstein explained it by treating light as made of particles (photons) of energy $h\nu$.
So the photoelectric effect shows the particle nature of light.

Concept Photoelectric effect shows photons

Dual Nature of Radiation and Matter in past papers

82 questions from this chapter have appeared across 27 exam years.