In $BrF_3$ molecule, the lone pairs occupy equatorial positions to minimize :-
A
Bond pair – bond pair repulsion only
B
Lone pair – lone pair repulsion and lone pair – bond pair repulsion
C
Lone pair – lone pair repulsion only
D
Lone pair – bond pair repulsion only
The answer is B.
Solution
In $BrF_3$, Br has 7 valence electrons; 3 form bonds with F and 4 remain as 2 lone pairs. So there are 5 electron pairs (3 bp + 2 lp), and the electron geometry is trigonal bipyramidal ($sp^3d$). Repulsions decrease in the order: lp–lp $\gt$ lp–bp $\gt$ bp–bp. In a trigonal bipyramid, an equatorial position has only two neighbours at $90^\circ$, whereas an axial position has three neighbours at $90^\circ$. So lone pairs placed in equatorial positions have fewer strong $90^\circ$ interactions. With both lone pairs equatorial, they are $120^\circ$ apart (reducing lp–lp repulsion), and each has fewer $90^\circ$ contacts with bond pairs (reducing lp–bp repulsion). This gives $BrF_3$ its T-shaped (slightly bent T) molecular shape. So the lone pairs occupy equatorial positions to minimise both lone pair–lone pair and lone pair–bond pair repulsions.
ConceptLone pairs in equatorial positions of trigonal bipyramid
VSEPR Theory in past papers
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