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Hydrocarbons
Effect of Branching on Boiling Point of Alkanes
1 question from 1 paper, each with its answer.
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- years asked, 2017–2026
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- of Hydrocarbons
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Concepts tested
- Branching, molecular shape and boiling point trend
All Questions
2024 1 question
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Given below are two statements:
Statement I: The boiling point of three isomeric pentanes follows the order n-pentane > isopentane > neopentane. Statement II: When branching increases, the molecule attains a shape of sphere. This results in smaller surface area for contact, due to which the intermolecular forces between the spherical molecules are weak, thereby lowering the boiling point. In the light of the above statements, choose the most appropriate answer from the options given below:n-pentane: $CH_3-CH_2-CH_2-CH_2-CH_3$; isopentane: $(CH_3)_2CH-CH_2-CH_3$; neopentane: $C(CH_3)_4$ When branching increases, the molecule attains a shape of a sphere. This results in a smaller surface area for contact, so the intermolecular forces between the spherical molecules are weak, lowering the boiling point. So n-pentane > isopentane > neopentane, and both statements are correct.
