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Solutions
Osmotic Pressure and van't Hoff Equation
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Concepts tested
- Determining temperature from slope of osmotic pressure vs concentration graph
All Questions
2024 1 question
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The plot of osmotic pressure ($\Pi$) vs concentration (mol L$^{-1}$) for a solution gives a straight line with slope 25.73 L bar $mol^{-1}$. The temperature at which the osmotic pressure measurement is done is: (Use $R = 0.083$ L bar $mol^{-1} K^{-1}$)$\Pi = CRT$; comparing with $y = mx$, the slope m = RT $T = \frac{slope}{R} = \frac{25.73}{0.083} = 310$ K $= (310 - 273)^\circ C = 37^\circ C$
